Synthesis and characterization of ruthenium (II) carbonyl complexes containing naphthyridine and acetylacetonate ligands and their catalytic activity in the hydrogen transfer reaction

نویسندگان

  • Sergio A. Moya
  • Juan Carlos Araya
  • Juana Gajardo
  • Véronique Guerchais
  • Hubert Le Bozec
  • Loïc Toupet
  • Pedro Aguirre
چکیده

a Universidad de Santiago de Chile, Facultad de Química y Biología, Avda. Libertador Bernardo O'Higgins 3363, casilla 40, correo 33, Santiago, Chile b Universidad Iberoamericana de Ciencias y Tecnología, Facultad de Ciencias, Departamento de Química, Chile c UMR 6226 CNRS-Université de Rennes 1, Sciences Chimiques de Rennes, Campus de Beaulieu, 35042 Rennes, France d UMR 6626 CNRS-Unversité de Rennes 1, Groupe Matière Condensée, Campus de Beaulieu, 35042 Rennes, France e Universidad de Chile, Facultad de Ciencias Químicas y Farmacéuticas, Santiago, Chile

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Synthesis, Characterization, Electrochemical and Spectroelectrochemical Properties of Ruthenium(II) Complexes Containing Phenylcyanamide Ligands and Effect of the Inner- Sphere on the Ru-NCN Chromophore

[Ru(terpy)(bpy)(L)]PF6 complexes, where terpy is 2,2΄:6′,2″– terpyridine, bpy is 2,2΄ - bipyridine and L is monoanions of  4 - bromophenylcyanamide (4 - Brpcyd), 4-methoxyphenylcyanamide (4 - MeOPcyd), 2, 4 - dibromophenylcyanamide (2,4 - Br2pcyd), 2,4-dimethylphenylcyanamide (2,4 - Me2pcyd), 2 - methylphenylcyanamide  (2 ...

متن کامل

Syntheses, Characterization and Solvatochromism Study of Heteroleptic Chelated Copper(II) Complexes Containing N,N- dibezyl Substituted Ethylenediamine and Acetylacetonate Ligands

A series of new heteroleptic chelated copper(II) complexes that encompass N,N-dibezyl substituted derivative of ethylenediamine (X-diamine) and acetylacetonate (acac) were prepared.  The IR and electronic absorption spectra and the molar conductivity of the complexes are presented and discussed.  The molar conductivity values of the complexes in different solvents reveals a predominance of elec...

متن کامل

New Tetraaza Schiff Base Ligands and Their Complexes: Synthesis, Characterization and Thermodynamic Studies

Some new symmetrical tetraaza Schiff base ligands containing 2-quinolinecarboxaldehyde moiety formed from condensation reaction of 2-quinolinecarboxaldehyde and o-phenylenediamine derivatives, such as N, Nˊ-bis(2-quinolylmethylidene)-4-methoxy-1, 2-phenylenediimine (L1), N, Nˊ-bis(2-quinolylmethylidene)-4-methy-1, 2-phenylenediimine (L2), N, Nˊ-bis(2-quinolylmethylidene)-4-chloro-1, 2-phenylene...

متن کامل

Synthesis and Metal Ion Uptake Studies of Silica Gel-Immobilized Schiff Base Derivatives and Catalytic Behaviors of their Cu(II) Complexes

New silica supported Schiff base ligands were prepared by the condensation reaction of 4,6-diacetylresorcinol with silica-gel derivatives, which modified with 3-aminopropyltriethoxysilane and N-(2-aminoethyl) -3-aminopropyltrimethoxysilane. Metal ion uptake capacities of these compounds were studied towards of selected transition metal (Cd(II), Cu(II), Co(II), Mn(II), Pb(II) and Ni(II)) cations...

متن کامل

Synthesis, Characterization and in Vitro Antimicrobial Screening of the Xanthate Derivatives and their Iron(II) Complexes

Seven reported xanthate ligands and their new Fe(II) complexes of formulaNa[Fe(R-OCSS)3], where R is ethyl-, propyl-, butyl-, pentyl-, Hexyl-, heptyl- and octyl-xanthate have been synthesized. They have been characterized using elemental analysis, molar conductance, FT-IR, UV-Vis and 1H NMR spectroscopic techniques and melting-, decomposition-points for ligand...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2012